On one of the LEC discs was a dos program called ... It allowed you to play the .san files (movie files).
Look for it on the dig cd, but It might've been another.
As for taking screenshots, I'm not sure about directly out of the game, but you could use a thirdparty screengrabber, windows probably, but you can get dos ones, and use that.
Some other people might have additional suggestions.
Of course you can use Scumm Revisited to get the background art. I think the latest version doesn't read some of the object images or the sound files, though an earlier version certainly does. But the recent version can see the costumes.
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