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I have no problems with Vista at all.
Mod compatibility is pretty much irrelevant, if the game runs then the mods also will run (so long as you don't try using a mod compiled for Linux on Windows, or anything daft like that).
So you'll have no problems with Vista 32-bit.
As for graphics cards, I have an 8-Series GeForce and it runs JA flawlessly, so again, you won't have too much of an issue there.
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